4 edition of Selective oxidation of hydrocarbons found in the catalog.
Includes bibliographical references.
|Statement||[by] D. J. Hucknall.|
|LC Classifications||TP156.O9 H82 1974|
|The Physical Object|
|Pagination||vii, 212 p.|
|Number of Pages||212|
|LC Control Number||73019013|
Infrared spectroscopy was used to obtain information on the mechanism of the selective oxidation of toluene and o-xylene over vanadium oxide catalysts. The interaction of these aromatic hydrocarbons and the products benzaldehyde and o-tolualdehyde with the surface of a V2O5/TiO2 monolayer catalyst was investigated at different temperatures. phase selective oxidation of hydrocarbons over a solid catalyst. Benzene, n-butane, and butenes are used. Recovery of maleic anhydride as a by product from phthalic anhydride manufacture provides small commercial amounts. In general, the production of maleic anhydride from hydrocarbons . Bifunctional catalysts for conversion of hydrocarbons contain metal sites next to acid sites. In the case of conversion of normal alkanes, the metal sites catalyze (de-)hydrogenation reactions and the acid sites isomerization and cracking reactions to obtain iso-alkanes of the same or reduced molecular weight, respectively Critical properties of these catalysts are the ratio of metal sites. Oxidation Catalysis”, edited by Daniel Duprez and Fabrizio Cavani, aims to give an overview of catalytic oxidation methods. It is divided in two parts, covering total and selective oxidation, and draws on the experience of a number of academic and industrial scientists. It is a broad and generally useful book.
Selective oxidation catalysis is used in production of roughly 25% of all important organic chemicals and intermediates used for making consumer and industrial products . . The abundance of natural gas from shale resources makes efficient catalytic oxidation of light hydrocarbons to more valuable intermediates particularly desirable.
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Selective oxidation of hydrocarbons [Hucknall, D. J] on *FREE* shipping on qualifying offers. Selective oxidation of hydrocarbonsCited by: Additional Physical Format: Online version: Hucknall, D.J. Selective oxidation of hydrocarbons. London, New York, Academic Press, (OCoLC) A catalyst for the selective oxidation of hydrocarbons to unsaturated aldehydes, acids, acid anhydrides, divinyls, or styrenes has to perform several functions.
First, it must supply a limited amount of oxygen to the reactant, sufficient to allow the formation of the desired product but not enough to allow complete by: Selective oxidation of hydrocarbons is a very important industrial process that uses catalysts commonly based on transition metal oxides that are often vanadium and molybdenum oxides.
Selective oxidation reactions can be classified into two types: those that involve only dehydrogenation and those that involve both dehydrogenation and oxygen. Cite this chapter as: Mizuno N., Hashimoto M., Sumida Y., Nakagawa Y., Kamata K.
() Selective Oxidation of Hydrocarbons with Molecular Oxygen Catalyzed Cited by: 1. The cytochrome P enzymes CYPB1 and CYPC1, which are from the bacterium Novosphingobium aromaticivorans DSM, can hydroxylate norisoprenoids with high activity and selectivity. With the goal of expanding and establishing their substrate range with a view to Selective oxidation of hydrocarbons book applications, the oxidation of a selection of cyclic alkanes, ketones and alcohols was Selective oxidation of hydrocarbons book.
The development of mild and efficient process for the selective oxidation of organic compounds by molecular oxygen (O 2) can be one of the key technologies for synthesizing paper discloses an efficient and mild synthesis protocol for the O 2-involved ethylbenzene (EB) photooxidation triggered by dihydroanthracene (DHA) auto- photooxidation in acetone under visible light.
1. Introduction. It has been well documented that supported Au particles can be very active oxidation catalysts.
The most well-known of these reactions is low temperature CO oxidation, but others, such as oxidation of hydrogen to hydrogen peroxide and selective oxidation of hydrocarbons including epoxidation of propene and oxidation of propane to acetone are also firmly.
selective oxidation. Another strongly prevailing principle is that of phase cooperation [10–13]. This states that high-performance oxidation catalysts must be of the multi-phase type, as the different functions required in performing the selective oxidation of a hydrocarbon are only adequately optimized when independent functionally.
The chapter also discusses recent developments including selective oxidations with environmentally benign oxidants, green oxidations with metal complexes, chemoselective C‐H bond oxidations, asymmetric oxyfunctionalizations, and oxygenation of hydrocarbons in tandem processes with in situ generated H 2 O 2.
The two major characteristic. KeiskiR.L., LeiviskäK., in Advances in Clean Hydrocarbon Fuel Processing, Photocatalytic reactors.
Photocatalysis has been studied as a method for the selective oxidation of aromatics and alkanes to corresponding oxygenated compounds. The production of high-value compounds from their relatively inexpensive raw materials has been studied recently more and more.
The selective oxidation of light hydrocarbons, especially propylene, is the most significant and well-studied process. Its products include important intermediates such as acrolein, acrylic acid, propylene oxide, etc.
The catalytic process was first discovered in by Hearne and Adams with the use of cuprous oxide catalysts. The activation of C–H bonds is an efficient approach for the production of value-added organics. The partial oxidation of hydrocarbons to oxygen-containing products at mild conditions is a profound challenge because the products are often more active than the substrates.
In this context, a novel helical structure of monoclinic scheelite bismuth vanadate (BiVO4) on the top of the silver (Ag.
This paper reviews the preparation techniques, characterization, and use of nickel molybdate catalysts in the selective oxidation of hydrocarbons, particularly of light alkanes. Catalysts with different Ni:Mo ratios, unsupported and supported, undoped and doped, were considered.
A systematic investigation of the oxidative dehydrogenation of propane to propene and 1- and 2-butene to 1,3-butadiene, and the selective oxidation of isobutene to methacrolein was carried out over Bi 1− x /3 V 1− x Mo x O 4 (x = 0–1) with the aim of defining the effects of catalyst and reactant composition on the reaction kinetics.
This work has revealed that the reaction kinetics can. Selective catalytic oxidation of hydrocarbons is challenging. Here, we show how this chemistry could be accomplished for cyclohexane (C 6 H 12) at room temperature with good turnover numbers, excellent catalytic efficiencies, high conversion yields and product selectivity, when the catalysis is mediated by a tricopper cluster complex immobilized in the nanochannels of mesoporous silica.
Selective Oxidation Of Hydrocarbons By Cobaltsubstituted Aluminophosphate Molecular Sieves - Volume - Victor A. Maroni, Lennox E. Iton. The selective oxidation of substituted aromatic hydrocarbons and the observation of uncoupling via redox cycling during naphthalene oxidation by the CYPB1 system E.
He is author of about 90 papers and reviews and 20 international patents, author of four books on oxidative and other dehydrogenation processes, selective partial oxidation of hydrocarbons, technology of catalytic oxidations other new developments in the field.
Article Views are the COUNTER-compliant sum of full text article downloads since November (both PDF and HTML) across all institutions and individuals. Catalyst [email protected] is highly active in the selective aerobic oxidation of hydrocarbons under mild and solvent-free conditions ( °C, MPa O 2, 5 h), showing the best conversion of % with % selectivity, and can be stably reused at least 6 times.
Heterogeneous Catalytic Oxidation; Fundamental and Technological Aspects of the Selective and Total Oxidation of Organic Compounds presents the essence of catalytic chemistry, describing the structure of catalysts, the technology in which they are used and the chemical transformations that.
isbn: oclc number: description: 1 online resource ( pages): illustrations: contents: selective catalytichydrocarbons oxidation:new perspectives; contents; preface; introduction; homogeneous catalytic oxidations ofalkylarens with molecular oxygen; methods for enhancing the activityand selectivity of homogeneouscatalysts in the oxidation processes; iii.
Abstract. The Gif system 1,2 for the selective oxidation of saturated hydrocarbons consists of pyridine (as solvent), acetic acid (or other carboxylic acid), zinc powder (as source of electrons), oxygen and an iron salt as catalyst.
The iron salt is rapidly complexed with ortho-dlpyrldyl (produced by reduction of pyridine).This system is interesting because it oxidizes hydrocarbons selectively.
Selective oxidation processes. [American Chemical Society. Division of Petroleum Chemistry.;] Book: All Authors / Contributors: American Chemical Society. Division of Petroleum Chemistry. OCLC Number: Notes: Oxidation of hydrocarbons in basic solution.
Series Title: Advances in chemistry series, A new type of superhydrophobic material, FP-Co-SiO2 was prepared with organic groups immobilized on the surface of the SiO2-based nanocomposite. This material showed much higher catalytic activity for selective oxidation of hydrocarbons than an equivalent hydrophilic catalyst.
Selective aerobic oxidation of hydrocarbons undergoes a free‐radical chain reaction to yield corresponding value‐added products is the significant process in the chemical industry. Nanocarbons with heteroatoms doping as free‐metal catalysts have been proved to be excellent alternatives in various fields of reactions.
Advances in Catalytic Technologies for Selective Oxidation of Lower Alkanes: /ch The main challenge for selective oxidation catalysis has always been achieving an economically viable selectivity.
In this chapter, the advances made around. A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices.
A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light.
The selective oxidation of hydrocarbons is a very important reaction taking place in industrial processes based on petroleum, since the oxygenated compounds produced can be used as intermediates for organic synthesis. However, the activation. Activation of molecular oxygen by a metal–organic framework with open 2,2′-bipyridine for selective oxidation of saturated hydrocarbons.
Chemical Communications48 (99), Selective oxidation of alkylarenes to aromatic acids/ketone in water by using reusable binaphthyl stabilized Pt nanoparticles (Pt-BNP) as catalyst.
Applied Catalysis B: Environmental, DOI: / Gibbs-Wohl Naphthalene Oxidation.DOI: /conrr hydrocarbons into valuable products or intermediates.
Selective oxidation catalysts provide a limited amount of oxygen to the hydrocarbon, allowing the formation of the desired product but preventing complete combustion. Some of the most important industrial selective oxidation catalysts are listed in.
selective oxidation of C4 hydrocarbons. Previous research has established the general redox behavior of V-P-0 catalysts; a Mars-van Krevelan type mechanism has been proposed involving and oxidation states .
A two-part approach was employed in this investigation. First the role of various surface layer oxygen, and the participation of bulk. Selective Thermal Oxidation of Hydrocarbons. This example describes general conditions used for selective thermal oxidation of hydrocarbons. Hydrocarbons and oxygen are loaded into the zeolite matrix, or pellet, used for experimental purposes according to Example 1.
Hydrocarbons and oxygen are loaded under several hundreds Torr pressure. This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation.
For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities.
Heterogeneous Hydrocarbon Oxidation by Barbara K. Warren,available at Book Depository with free delivery worldwide. Metal-Free: An Efficient and Selective Catalytic Aerobic Oxidation of Hydrocarbons with Oxime and N -Hydroxyphthalimide. Advanced Synthesis & Catalysis(16), DOI: /adsc This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation.
For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial.
Selective oxidation of hydrocarbons catalyzed by heteropoly compounds (M. Misono et al.). Plenary Lectures. Molecular approach to active sites on metallic oxides for partial oxidation reactions (J.C. Védrine). Reductive and oxidative activation of oxygen for selective oxygenation of hydrocarbons.
General information about Polynuclear Aromatic Hydrocarbons (PAHs) 1 Heavy oils, resids, bitumens upgrading 3 General Information 3 Common methods of heavy crudes upgrading 5 Oxidation as a possible pathway in upgrading of bottom of the barrel compounds 6 Chemistry of selective oxidation 8 General.Selective oxidation of saturated hydrocarbon, on the other hand, can be accomplished using a mixture of H 2 and O 2.
For example, propane can be oxidized to acetone. This reaction, however, appears to require a Au particle in the proximity of a titanyl moiety.COVID Resources. Reliable information about the coronavirus (COVID) is available from the World Health Organization (current situation, international travel).Numerous and frequently-updated resource results are available from this ’s WebJunction has pulled together information and resources to assist library staff as they consider how to handle coronavirus.